Corresponding-author research paper
Slightly Hydrogen-Ordered State of Ice IV Evidenced by In-Situ Neutron Diffraction
The Journal of Physical Chemistry Letters (2023)
Hiroki Kobayashi*, Kazuki Komatsu, Hayate Ito, Shinichi Machida, Takanori Hattori, and Hiroyuki Kagi.
Many ice polymorphs comprise a hydrogen disorder-order pair, but a metastable high-p phase ice IV lacks its hydrogen-ordered counterpart. Here, we report crystallographic evidence for weak hydrogen ordering in DCl-doped ice IV upon cooling for the first time based on in-situ neutron diffraction observations. We have gotten the tail of a new ice - but we also think that our sample suffered from large kinetic effects that hampers the structural transformation at low temperatures. More ordered samples are needed to finally declare the discovery of a new phase.